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N-[(3R)-6-(5,6-dihydropyridin-2-yl)-7-hydroxy-8-[(2E)-1-hydroxybut-2-en-1-yl]-2-oxo-1,5-oxathiocan-3-yl]acetamide + acceptor <=> N-[(3R)-8-[(2E)-but-2-enoyl]-6-(5,6-dihydropyridin-2-yl)-2-oxo-4,8-dihydro-3H-1,5-oxathiocin-3-yl]acetamide + H2O + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18630
|
|
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|
(1E,3S,4Z)-7-amino-1-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}hepta-1,4-dien-3-ol + O2 + FADH2 <=> (1S,2Z)-5-amino-1-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)pent-2-en-1-ol + H2O + FAD + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18635
|
|
|
|
(3Z,5S,6E,8E,10E)-1-aminododeca-3,6,8,10-tetraen-5-ol + O2 + FADH2 <=> (1E,3S,4Z)-7-amino-1-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}hepta-1,4-dien-3-ol + H2O + FAD + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18636
|
|
|
|
(2E,5S,6E,8E,10E)-1-aminododeca-2,6,8,10-tetraen-5-ol <=> (3Z,5S,6E,8E,10E)-1-aminododeca-3,6,8,10-tetraen-5-ol
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18637
|
|
|
|
N-acetyl-L-cysteine + 2-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)-5,6-dihydropyridine <=> (2R)-3-{[1-(5,6-dihydropyridin-2-yl)-2-hydroxy-2-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}ethyl]sulfanyl}-2-acetamidopropanoate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18632
|
|
|
|
malonyl-CoA + NADPH + NADH + H+ <=> (2E,5S,6E,8E,10E)-5-hydroxydodeca-2,6,8,10-tetraenal + CoA + CO2 + NADP+ + NAD+ + H2O
|
2.3.1.281
5-hydroxydodecatetraenal polyketide synthase
|
–
|
| |
BRENDA:
BR52683
KEGG:
R12337
MetaCyc:
RXN-18628
|
|
|
|
(2R)-3-{[1-(5,6-dihydropyridin-2-yl)-2-hydroxy-2-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}ethyl]sulfanyl}-2-acetamidopropanoate + H+ <=> N-[(3R)-6-(5,6-dihydropyridin-2-yl)-7-hydroxy-8-[(2E)-1-hydroxybut-2-en-1-yl]-2-oxo-1,5-oxathiocan-3-yl]acetamide
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18631
|
|
|
|
(1S,2Z)-5-amino-1-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)pent-2-en-1-ol + FAD <=> 2-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)-5,6-dihydro-1H-pyridin-2-ol + FADH2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18634
|
|
|
|
(2E,5S,6E,8E,10E)-1-aminododeca-2,6,8,10-tetraen-5-ol + pyruvate <=> (2E,5S,6E,8E,10E)-5-hydroxydodeca-2,6,8,10-tetraenal + L-alanine
|
2.6.1.115
5-hydroxydodecatetraenal 1-aminotransferase
|
–
|
| |
BRENDA:
BR52692
KEGG:
R12343
MetaCyc:
RXN-18638
|
|
|
|
N-[(3R)-8-[(2E)-but-2-enoyl]-6-(5,6-dihydropyridin-2-yl)-2-oxo-4,8-dihydro-3H-1,5-oxathiocin-3-yl]acetamide <=> coelimycin_P1
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18629
|
|
|
|
2-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)-5,6-dihydro-1H-pyridin-2-ol <=> 2-(3-{3-[(1E)-prop-1-en-1-yl]oxiran-2-yl}oxiran-2-yl)-5,6-dihydropyridine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18633
|
|
